Lithium-Ion Vs Lead-Acid Battery

When it comes to choosing the right battery for your application, you likely have a list of conditions you need to fulfill. How much voltage is needed, what is the capacity requirement, cyclic or standby, etc.

Once you have the specifics narrowed down you may be wondering, “do I need a lithium battery or a traditional sealed lead acid battery?” Or, more importantly, “what is the difference between lithium and sealed lead acid?” There are several factors to consider before choosing a battery chemistry, as both have strengths and weaknesses.

For the purpose of this blog, lithium refers to Lithium Iron Phosphate (LiFePO4) batteries only, and SLA refers to lead acid/sealed lead acid batteries

CYCLIC PERFORMANCE LITHIUM VS SLA

The most notable difference between lithium iron phosphate and lead acid is the fact that the lithium battery capacity is independent of the discharge rate. The figure below compares the actual capacity as a percentage of the rated capacity of the battery versus the discharge rate as expressed by C (C equals the discharge current divided by the capacity rating) With very high discharge rates, for instance .8C, the capacity of the lead acid battery is only 60% of the rated capacity. Find out more about C rates of batteries.

Therefore, in cyclic applications where the discharge rate is often greater than 0.1C, a lower rated lithium battery will often have a higher actual capacity than the comparable lead acid battery. This means that at the same capacity rating, the lithium will cost more, but you can use a lower capacity lithium for the same application at a lower price. The cost of ownership when you consider the cycle, further increases the value of the lithium battery when compared to a lead acid battery.

The second most notable difference between SLA and Lithium is the cyclic performance of lithium. Lithium has ten times the cycle life of SLA under most conditions. This brings the cost per cycle of lithium lower than SLA, meaning you will have to replace a lithium battery less often than SLA in a cyclic application.

CHARGING TIMES OF LITHIUM AND SLA

Charging SLA batteries is notoriously slow. In most cyclic applications, you need to have extra SLA batteries available so you can still use your application while the other battery is charging. In standby applications, an SLA battery must be kept on a float charge.

With lithium batteries, charging is four times faster than SLA. The faster charging means there is more time the battery is in use, and therefore requires less batteries. They also recover quickly after an event (like in a backup or standby application). As a bonus, there is no need to keep lithium on a float charge for storage. For more information on how to charge a lithium battery, please view our Lithium Charging Guide.

HIGH TEMPERATURE BATTERY PERFORMAN

Lithium’s performance is far superior than SLA in high temperature applications. In fact, lithium at 55°C still has twice the cycle life as SLA does at room temperature. Lithium will outperform lead under most conditions but is especially strong at elevated temperatures.

Cycle life vs various temperatures for LiFePO4 batteries

COLD TEMPERATURE BATTERY PERFORMANCE

Cold temperatures can cause significant capacity reduction for all battery chemistries. Knowing this, there are two things to consider when evaluating a battery for cold temperature use: charging and discharging. A lithium battery will not accept a charge at a low temperature (below 32° F). However, an SLA can accept low current charges at a low temperature.

Conversely, a lithium battery has a higher discharge capacity at cold temperatures than SLA. This means that lithium batteries do not have to be over designed for cold temperatures, but charging could be a limiting factor. At 0°F, lithium is discharged at 70% of its rated capacity, but SLA is at 45%.

One thing to consider in cold temperature is the state of the lithium battery when you want to charge it. If the battery has just finished discharging, the battery will have generated enough heat to accept a charge. If the battery has had a chance to cool down, it may not accept a charge if the temperature is below 32°F.

BATTERY INSTALLATION

If you have ever tried to install a lead acid battery, you know how important it is to not install it in an invert position to prevent any potential issues with venting. While an SLA is designed to not leak, the vents allow for some residual release of the gasses.

Lithium-Ion vs Lead-Acid battery